{4,4′,6,6′-Tetraiodo-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ4 O,N,N′,O′}nickel(II)
نویسندگان
چکیده
The asymmetric unit of the title compound, [Ni(C(17)H(12)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) and central C atom of the propyl chain are located on a twofold rotation axis. The geometry around the Ni(II) atom is square planar, supported by the N(2)O(2) donor atoms of the coordinated ligand. In the crystal, there are no significant inter-molecular inter-actions present. The crystal studied was a non-merohedral twin with a refined twin component ratio of 0.944 (1):0.056 (1).
منابع مشابه
{4,4′,6,6′-Tetraiodo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II)
The asymmetric unit of the title compound, [Ni(C(19)H(16)I(4)N(2)O(2))], comprises half of a Schiff base complex. The Ni(II) atom is located on a twofold rotation axis which also bis-ects the central C atom of the 2,2-dimethyl-propane group of the ligand. The geometry around the Ni(II) atom is distorted square-planar, with a dihedral angle of 21.7 (3)° between the symmetry-related N/Ni/O coordi...
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